Search results for "Ate complex"
showing 10 items of 30 documents
The Average State Complexity of the Star of a Finite Set of Words Is Linear
2008
We prove that, for the uniform distribution over all sets Xof m(that is a fixed integer) non-empty words whose sum of lengths is n, $\mathcal{D}_X$, one of the usual deterministic automata recognizing X*, has on average $\mathcal{O}(n)$ states and that the average state complexity of X*is i¾?(n). We also show that the average time complexity of the computation of the automaton $\mathcal{D}_X$ is $\mathcal{O}(n\log n)$, when the alphabet is of size at least three.
Synthesis, X-ray Structure, Antimicrobial and Anticancer Activity of a Novel [Ag(ethyl-3-quinolate)2(citrate)] Complex
2022
A novel Ag(I) citrate complex with ethyl-3-quinolate (Et3qu) was synthesized. Its structure was confirmed using X-ray single crystal to be [Ag(Et3qu)2(citrate)]. It crystallized in the Triclinic crystal system and P-1 space group with unit cell parameters of a = 8.6475(2) Å, b = 11.4426(3) Å, c = 15.2256(3) Å, α = 73.636(2)°, β = 79.692(2)° and γ = 86.832(2)°, while the unit cell volume was 1422.19(6) Å3. In the unit cell, there are two [Ag(Et3qu)2(citrate)] molecules and one unit as the asymmetric formula. The molecular structure comprised one Ag(I) coordinated with two Et3qu molecules via two almost equidistant Ag-N bonds and one citrate ion acting as a mono-negative monodentate ligand vi…
Error-Free Affine, Unitary, and Probabilistic OBDDs
2021
We introduce the affine OBDD model and show that zero-error affine OBDDs can be exponentially narrower than bounded-error unitary and probabilistic OBDDs on certain problems. Moreover, we show that Las-Vegas unitary and probabilistic OBDDs can be quadratically narrower than deterministic OBDDs. We also obtain the same results for the automata counterparts of these models.
Structural chemistry of complexes of ( ? 1)d s metal ions with ?-N-donor substituted thiolate ligands (=0, 2)
2005
Abstract The molecular structures of several d 10 metal ion complexes with 2-amino or 2-imino substituted thiolate ligands, derived from 2-aminoethanethiol, 2-(mercaptomethyl)pyridine, 2-aminobenzenethiole, and 8-mercaptoquinoline, are presented. Since ligand field stabilization energy is absent, the complexes display a large variety of co-ordination numbers and geometries around the metal centers. Distortions from ideal tetrahedral or trigonal bipyramidal configurations are discussed in terms of special structural parameters. In contrast to thiolate ligands that lack additional donor atoms and thus form oligo- or poly-nuclear complexes, the β-N donor group stabilizes mono-nuclear complexes…
Quantum dynamics of the oxygen isotopic exchange : lifetimes of metastable states of the ozone intermediate complex
2021
This thesis aims to describe the ozone dynamics during the isotopic exchange reactions of oxygen of type xO + yO zO (xO yO zO)* xO yO + zO, where x, y and z are the atomic masses of the stable oxygen isotopes (16, 17, 18). Firstly, we analyze several methods of accurate description of the atom interactions and numerical schemes to obtain the observables for the collision. Then, in a full-quantum hyperspherical formalism, we study the actual dynamics of the reactive process O + O2 -> O3* -> O2 + O. The metastable ozone created can then either decompose into oxygen by the inverse reaction, or relax into stable ozone by exchanging energy with the environment, typically N2 or O2 molecules. Thes…
The average state complexity of rational operations on finite languages is linear
2010
Considering the uniform distribution on sets of m non-empty words whose sum of lengths is n, we establish that the average state complexities of the rational operations are asymptotically linear.
A new copper(II) chelate complex with tridentate ligand: Synthesis, crystal and molecular electronic structure of aqua-(diethylenetriamine-N, N′, N′′…
2015
Abstract The crystals of a new aqua-(diethylenetriamine-N, N′, N′′)-copper(II) sulfate monohydrate have been synthesized by direct interaction of solid copper(II) sulfate pentahydrate with diethylenetriamine (deta). The crystal structure of [Cu(deta)H2O]SO4⋅H2O (1) has been determined by X-ray diffraction methods at 100 K and characterized using X-ray powder diffraction pattern: space group P 1 ¯ , a = 7.2819(4), b = 8.4669(4), c = 8.7020(3) A, α = 83.590(3), β = 89.620(4), γ = 84.946(4)°, Z = 2. The environment of the Cu(II) atom is a distorted, elongated square pyramid which consists of three nitrogen atoms of the deta molecule and oxygen atom of the water molecule in the basal plane of t…
Counting with Probabilistic and Ultrametric Finite Automata
2014
We investigate the state complexity of probabilistic and ultrametric finite automata for the problem of counting, i.e. recognizing the one-word unary language \(C_n=\left\{ 1^n \right\} \). We also review the known results for other types of automata.
Hydrogen-Bonded Open-Framework with Pyridyl-Decorated Channels: Straightforward Preparation and Insight into Its Affinity for Acidic Molecules in Sol…
2017
International audience; An hydrogen-bonded open framework with pores decorated by pyridyl groups has been constructed following an off-charge-stoichiometry assemblage of protonated tetrakis(4-pyridyl-oxymethyl)methane and [Al(oxalate)3]3-, respectively the H-bond donor and acceptor of the ionic H-bond interactions. This supramolecular porous architecture (SPA-2) possesses 1 nm-large pores interconnected in 3D with high solvent accessible void (53%). It demonstrated remarkable affinity for acidic organic molecules in solution, which was investigated by the means of various carboxylic acids including larger drug molecules. Noteworthy, competing sorption between acetic acid and its halogenated…
Retarded Elimination of a High-Molecular Enzyme-Substrate-Complex after Hydroxyethyl-Starch-Infusion
1978
During a pharmacokinetic study with hydroxyethyl starch we found, that this plasma substitute induces a regular increase of serum amylase. In 54 patients after infusion of 500 ml 6% hydroxyethyl starch (HES) an increase of serum amylase was observed, which in 51 cases exceeded the upper limit of normal (190 U/l). In most cases serum amylase reached values twice as high as the basal value. Renal function influenced duration of increased serum amylase values, but did not influence maximum increases (201 ±15 U/l; mean ± SEM). In patients with advanced renal failure (GFR = 2–10 ml/min) serum amylase was still markedly elevated after 72 hours (298 ± U/l; mean ± SEM). In patients with normal rena…